A single-chain magnet based on linear [Mn(III)2Mn(II)] units.

نویسندگان

  • Constantina Papatriantafyllopoulou
  • Sotiris Zartilas
  • Manolis J Manos
  • Céline Pichon
  • Rodolphe Clérac
  • Anastasios J Tasiopoulos
چکیده

The synthesis, structural characterization and magnetic properties of a 1D coordination polymer based on a linear mixed valent [Mn(III)2Mn(II)] repeating unit are described. It displays single-chain magnet (SCM) behaviour with an energy barrier of ∼38 K and represents the first example of a mixed valent Mn-carboxylate SCM with a linear architecture.

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عنوان ژورنال:
  • Chemical communications

دوره 50 94  شماره 

صفحات  -

تاریخ انتشار 2014